| Synthesis and Characterization of Cyclopentadithiophene and Thienothiophene-Based Polymers for Organic Thin-Film Transistors and Solar Cells | |||||
| 작성자 | 김** | 작성일 | 2019-07-29 | 조회수 | 81 |
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Journal Article published Oct 2018 in Macromolecular Research volume 26 issue 10 on pages 934 to 941
AbstractNovel donor-donor type alternating copolymers (8CDT-TT and 16CDT-TT) derived from cyclopentadithiophene (CDT) and thienothiophene (TT) moieties that differ from solubilizing side chains were successfully synthesized and characterized. After the synthesis of CDT-TT-based conjugated polymers with dioctyl and dihexadecyl side chains, their optical, thermal, structural and semiconducting properties were investigated. Organic thin-film transistors fabricated from 8CDT-TT and 16CDT-TT exhibit carrier mobilities as high as 3.92×10-4 and 1.05×10-3 cm2V-1s-1, respectively. Bulk heterojunction solar cells fabricated using a polymer:PCBM blend ratio of 1:3 exhibit power conversion efficiencies of 2.12 and 1.84% for 8CDT-TT and 16CDT-TT, respectively. |
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